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Publications

Cross-coupling between Aryl Halides and Aryl Alkynes Catalyzed by an Odd Alternant Hydrocarbon

Sil, S.; Krishnapriya, A. U.; Mandal, P.; Kuniyil, R.;* Mandal, S. K.*
Chem. Eur. J. 2024, Accepted

Exploiting N-Centered Umpolung Reactivity of α-Iminomalonates for the Synthesis of N-Sulfenylimines and Sulfonamides

Roy, S.; Krishnapriya, A. U.;' Chakraborty, Arijit.;' Kuniyil, R.;* Chatterjee, I.*
Org. Lett. 2024, Accepted ('Authors contributed equally)

​Regioselective 1,2-Alkylboration of Benzylidenecyclopropanes: Access to Csp3-Enriched Cyclopropyl Boronic Esters

Mondal, P.; Nair, A.;' Megha, S.;' Chungath, A.;' Suman, S.; Kuniyil, R.;* Sahoo, B.*
Org. Lett. 2024, Accepted ('Authors contributed equally)

Selective Synthesis of Functionalized Linear Aliphatic Primary Amines via Decarboxylative Radical Polar Crossover Process

Cauwenbergh, R.; Sahoo, P.; Maity, R.; Mathew, A.; Kuniyil, R.; Das, S.*
Green Chem. 2024, Accepted 

Redox-Neutral Decarboxylative Cross-Coupling of Oxamates with Arylbromides

Bisoy. A.; Simhadri, V.; Surya, K.; Kuniyil, R.;* Yatham, V. R.*
ACS Org Inorg Au. 2023, Accepted

Redox-Neutral Radical Cascade Cyclization of N-Arylacrylamides with Unactivated Alkyl and Aryl Chlorides

Jha, A. K.; Nair, D. P.; Munaifa, A.; Yedase, G.; Kuniyil, R.;* Yatham, V. R.*

J. Org. Chem. 2023, Accepted

Copper(I)-Catalyzed Decarboxylative N-Phosphorylation: Modular Preparation of N-Acyl Iminophosphoranes Using Dioxazolones and Phosphines​​

Park, J.;' Krishnapriya, A. U.;' Park, Y.; Kim, M.; Reidl, T. W.; Kuniyil, R.;* Son, J.* 

Adv. Synth. Catal. 2023, Accepted ('Authors contributed equally)

Amine-rich Nickel(II)-Xerogel as a Highly Active Bifunctional Metallo-organo Catalyst for Aqueous Knoevenagel Condensation and Solvent-free CO2 Cycloaddition

Saha, E.; Jungi, H.; Dabas, S.; Mathew, A.; Kuniyil, R.;* Subramanian, S.;* Mitra, J.* 

Inorg. Chem. 2023, Accepted

Photocatalytic Hydro Tri/Difluoromethylation of Alkenes with Bench Stable Tri/Difluoro Methylating Reagents

Girish, Y.; Munaifa, A.; Kuniyil, R.;* Yatham, V. R.*

Org. Lett. 2023, Accepted

Dynamic Kinetic Stereoselective Glycosylation via Rh(II) and Chiral Phosphoric Acid-Cocatalyzed Carbenoid Insertion to Anomeric OH Bond for the Synthesis of Glycoconjugates 

Wu, J.; Jia, P.; Kuniyil, R.; Liu, P.; Tang, W.

Angew. Chem. Int. Ed. 2023, Accepted

Ruthenium-Catalyzed Selective α-Alkylation of β-Naphthols using Primary Alcohols: Elucidating the Influence of Base and Water

Sankar, R. V.; Mathew, A.; Pradhan, S.; Kuniyil, R.;* Gunanathan, C.*

Chem. Eur. J. 2023, Accepted

Generation of Photoinduced Phenalenyl-Based Radical: Towards Designing Reductive C-C Coupling Catalysis

Datta, P.; Goswami, T.; Kandoth, N.; Banik, A.; Ahmed, J.; Bhaskaran, A. S.; Saha, R.; Kuniyil, R.; Ghosh, H. N.; Mandal, S. K

ChemPhotoChem 2023, Accepted 

Reduced-Phenalenyl-Based Molecule as a Super Electron Donor for Radical-Mediated C–N Coupling Catalysis at Room Temperature

Sil, S.; Bhaskaran, A. S.; Chakraborty, S.; Singh, B.; Kuniyil, R.;* Mandal, S. K*

J. Am. Chem. Soc. 2022, 144, 22611–22621

Nickel-Catalyzed Dearomative Arylboration of Indoles: Regioselective Synthesis of C2- and C3-Borylated Indolines

Trammel, G. L.; Kuniyil, R.; Crook, P. F.; Liu, P.; Brown, M. K.

J. Am. Chem. Soc. 2021, 143, 16502–16511

Electrocatalytic C–H phosphorylation through nickel (III/IV/II) catalysis

 Zhang, S. K; Vecchio, A. D.; Kuniyil, R.; Messinis, A. M.; Lin, Z.; Ackermann, L.

Chem. 2021, 7, 1379-1392

Rhodaelectro-catalyzed chemo-divergent C–H activations with alkylidene cyclopropanes for selective cyclopropylations

Shen, Z.; Maksso, I.; Kuniyil, R.; Rogge, T.; Ackermann, L.

Chem. Commun. 2021, 57, 3668-3671

Understanding the unique reactivity patterns of nickel/JoSPOphos manifold in the nickel-catalyzed enantioselective C–H cyclization of imidazoles

Liu, J. B.; Wang, X.; Messinis, A. M.; Liu, X. J.; Kuniyil, R.; Chen, D. Z.; Ackermann, L.

Chem. Sci. 2021 12, 718-729

Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation

Wang, W.; Wu, J.; Kuniyil, R.; Lima, R. N.; Ackermann, L.

Chem. 2020, 6, 3428-3439

Electrochemical B–H Nitrogenation: Access to Amino Acid and BODIPY-Labeled nido-Carboranes

Yang, L.; Jei, B. B.; Scheremetjew, A.; Kuniyil, R.; Ackermann, L. 

Angew. Chem. Int. Ed. 2020, 60, 1482-1487

Recyclable Ruthenium Catalyst for Distal meta-C–H Activation

Choi, I.; Müller, V.; Wang, Y.; Xue, K.; Kuniyil, R.; Andreas, L. B.; Karius, V.; Alauzun, J. G.; Ackermann, L.  

Chem. Eur. J. 2020, 26, 15290

Reactivity-Controlling Factors in Carboxylate-Assisted C–H Activation under 4d and 3d Transition Metal Catalysis

Rogge, T.; Oliveira, J.; Kuniyil, R.; Hu, L.; Ackermann, L. 

ACS Catal. 2020, 10, 10551-10558

Photo-Induced Ruthenium-Catalyzed C–H Arylations at Room Temperature

Korvorapun, K.; Struwe, J.; Kuniyil, R.; Zangarelli, A.; Casnati, A.; Waeterschoot, M.; Ackermann, L.

Angew. Chem. Int. Ed. 2020, 59, 18103-18109

Insights into Ruthenium(II/IV)-Catalyzed Distal C–H Oxygenation by Weak Coordination

Bu, Q.;* Kuniyil, R.;* Zhigao, S.; Gońka, E.; Ackermann, L.

Chem. Eur. J. 2020, 26, 16450

Aza-Ruthena(II)-Bicyclo- [3.2.0]-Heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-Catalyzed Alkyne Annulations

Yang, L.; Steinbock, R.; Scheremetjew, A.; Kuniyil, R.; Finger, L. H.; Messinis, A.; Ackermann, L.

Angew. Chem. Int. Ed. 2020, 59, 11130-11135

Regioselective B(3,4)–H Arylation of o-Carboranes by Weak Amide Coordination at Room Temperature

Liang, Y.-F.; Yang, L.; Jei, B. B.; Kuniyil, R.; Ackermann, L.

Chem. Sci. 2020, 11, 10764-10769

Domino C–H Activation/Directing Group Migration/Alkyne Annulation: Unique Selectivity by d6-Cobalt(III) Catalysts

Zhu, C.; Kuniyil, R.; Jei, B. B.; Ackermann, L.

ACS Catal. 2020, 10, 4444-4450

C−H Oxygenation Reactions Enabled by Dual Catalysis with Electrogenerated Hypervalent Iodine Species and Ruthenium Complexes

Massignan, L.; Tan, X.; Meyer, T. H.; Kuniyil, R.; Messinis, A. M.; Ackermann, L.

Angew. Chem. Int. Ed. 2020, 59, 3184-3189

Late-Stage Diversification by Selectivity Switch in meta-C–H Activation: Evidence for Singlet Stabilization

Massignan, L.; Tan, X.; Meyer, T. H.; Kuniyil, R.; Messinis, A. M.; Ackermann, L.

Angew. Chem. Int. Ed. 2020, 59, 3184-3189

Catalyst-Free, Direct Electrochemical Synthesis of Annulated Medium-Sized Lactams through C‒C Bond Cleavage

Xu, Z.; Huang, Z.; Li, Y.; Kuniyil, R.; Zhang, C.; Ackermann, L.; Ruan, Z.

Green Chem. 2020, 22, 1099-1104

π-Extended Polyaromatic Hydrocarbons by Sustainable Alkyne Annulations through Double C–H/N–H Activation

Gońka, E.; Yang, L.; Steinbock, R; Pescaioli, F.; Kuniyil, R.; Ackermann, L.

Chem. Eur. J. 2019, 25, 16246-16250

Flow Rhodaelectro-Catalyzed Alkyne Annulations by Versatile C−H Activation: Mechanistic Support for Rhodium(III/IV)

Kong, W.-J.; Finger, L. H.; Messinis, A. M.; Kuniyil, R.; Oliveira, J. C. A.; Ackermann, L.

J. Am. Chem. Soc. 2019, 141, 17198-17206

BODIPY-Labeled Cyclobutanes by Secondary C(sp3)─H Arylations for Live-Cell Imaging

Virelli, M.; Wang, W.; Kuniyil, R.; Wu, J.; Zanoni, G.; Fernandez, A.; Scott, J.; Vendrel, M.; Ackermann, L.

Chem. Eur. J. 2019, 25, 12712-12718

Manganese(I)-Catalyzed C–H Activation/Diels-Alder/retro-Diels-Alder Domino Alkyne Annulation by Transformable Pyridines

Zhu, C.; Kuniyil, R.; Ackermann, L.

Angew. Chem. Int. Ed. 2019, 58, 5338-5342

Late-Stage Peptide Diversification by Cobalt-Catalyzed C– H Activation: Sequential Multicatalysis for Stapled Peptides

Lorion, M. M.; Kaplaneris, N.; Son, J.; Kuniyil, R.; Ackermann, L.

Angew. Chem. Int. Ed. 2019, 58, 1684-1702

Rutheniumcatalyzed C–H oxygenation of quinones by weak O-coordination for potent trypanocidal agents

Dias, G. G.; Rogge, T.; Kuniyil, R.; Jacob, C.; Menna-Barreto, R. F. S.; da Silva Júnior, E. N.; Ackermann, L.

Chem. Commun. 2018, 54, 12840-12843

Benzoate cyclometalation enables oxidative addition of haloarenes at a Ru (II) center

Simonetti, M.; Kuniyil, R.; Macgregor, S.; Larrosa, I

J. Am. Chem. Soc. 2018, 140, 11836-11847

Domino Process toward Functionally Dense Quaternary Carbons through Pd-Catalyzed Decarboxylative C(sp3)–C(sp3) Bond Formation

Guo, W.; Kuniyil, R.; Gómez, J. E.; Maseras, F.; Kleij, A. W. A

J. Am. Chem. Soc. 2018, 140, 3981-3987

Computational study on the mechanism of the reaction of carbon dioxide with siloxy silanes

Kuniyil, R.; Maseras, F.

Theor. Chem. Acc. 2017, 136, 1-7

Stereoselective and Versatile Preparation of Tri-and Tetrasubstituted Allylic Amine Scaffolds under Mild Conditions

Guo, W.; Rodríguez, L. M.; Kuniyil, R.; Martin, E.; Adan, E. C. E.; Maseras, F.; Kleij, A. W.

J. Am. Chem. Soc. 2016, 138, 11970- 11978

N-Heterocyclic Carbene Catalyzed Asymmetric Intermolecular Stetter Reaction: Origin of  Enantioselectivity and Role of Counterions

Kuniyil, R.; Sunoj, R. B.

Org. Lett. 2013, 15, 5040-5043

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